• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Heavy metal compounds are removed from the filter dust of industrial plants by thermal separation, by heating of the filter dust in a reaction vessel (4) up to the vaporisation temperature and quenching of the resulting heavy metal vapours in a cooler (13), condensing, subliming and taking off. Carrier gas (9) or circulating gas (16) is used for fluidising the filter dust, or a vacuum pump (32) is used for vaporising the heavy metal compounds under reduced pressure. Additives are used for promoting the vaporisation or conversion of the heavy metals into more volatile compounds. In plants operating continuously or discontinuously, the fine dust is advantageously separated off before the removal of the heavy metals and further treated separately. <IMAGE>
    公开号:SU1739858A3
    申请号:SU884356213
    申请日:1988-07-14
    公开日:1992-06-07
    发明作者:Гесингер Гернот；Йозеф Мирбах Манфред；Иохум Иоахим；Викерт Кристиан
    申请人:Ббц Браун Бовери Аг (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to the improvement, improvement and simplification of the release of separately processed harmful substances from the complex mixture of particles resulting from the combustion process.
    In particular, the invention concerns a method for extracting heavy metal compounds from filter-trapped dust from incineration plants, flue gas dedusting and gas cleaning systems by evaporation, separation and subsequent condensation and / or sublimation of heavy metal compounds.
    The aim of the invention is more complete removal of heavy non-ferrous metals.
    Example 1. In a small pilot plant, the dust collected by the filter from the incinerator is treated. The reactor is made of ceramic material and is cylindrical in shape. Its internal diameter is 50 mm, its height (inside,
    VI SAO 00 SL 00

    CJ
    31
    cylindrical part) 200 MNU The cooler consists of a double-walled stainless steel pipe with an inner diameter of 10 mm and a length of 1000 mm. Water passes through the cooling jacket as a cooling medium.
    The dust caught by the filter contains the following metals,%: Ca 11.5; C, - 0.09; Zn 3.3; Pb 0.8; Cd 0.05; Sn 0.34; Sb 0.16; Ba 0.34,
    10 g of dust collected by the filter are loaded into the reactor and heated to 1000 ° C. At this temperature, the dust is fluidized using a stream of nitrogen as a carrier gas and is maintained in a fluidized bed in a suspended state. The heavy metal compounds in the reactor are largely evaporated and continuously condensed in the cooler. At the same time, the precipitated metal salts are only slightly contaminated by ultrafine particles entrained in the gas flow. After 1 h, the process is completed and the reactor is cooled.
    The dust collected by the filter is analyzed before and after the thermal separation of heavy metal compounds. At the same time receive the following:
    Before separation- After separation
    walkie talkies 8.0
    0.3 0.4 0.005
    In addition, samples of dust collected by the filter are dissolved before and after thermal separation with saturated C0g water, and the resulting solutions are examined for the content of heavy metal ions:
    Heavy metal
    Zn2 + Pb2 + - C
    EXAMPLE 2 In the pilot plant, the dust collected from the incinerator installation is treated like in example 1. The installation is mounted similarly to the installation in example 1, but is large in size.
    1000 g is loaded into the reactor
    dust filter and for 3 h is maintained at a temperature of 1000 ° C. Instead of nitrogen, used acidic waste gas is used as a carrier gas. gas incinerator installation. After the batch is complete, the reactor is cooled and the residue is examined. Get the following result:
    five
    five
    Analyzed
    Before separation
    After separation of 8.2
    total mass, 10.0 g
    Content
    Zn% 3.3 0.02
    Content
    Pb,% 0.8 0.3
    Content
    Cd% 0.05 0.003
    In addition, samples of dust collected by the filter are dissolved before and after thermal separation with saturated CO2 water, and the resulting solutions are examined for the content of ions of the same
    five
    0
    five
    0
    LYH metals:
    T yellow
    metal
    Before separation. (Mg / l solution)
    After separation (mg / l solution) 1.3 2 1
    Zn2 + 1600 Pb2 13 Cd2-1 37
    It follows that by using a reactive gas instead of inert nitrogen, the best result is obtained for the extraction of heavy metals from dust collected by the filter.
    Example In a pilot plant for continuous operation, the dust collected by the filter from the incinerator is prepared. The reactor is made of a refractory ceramic material and has a shell-shaped thermal insulation also made of a ceramic material and glass felt. The cylindrical inner space has a diameter of 100 mm and a height of 500 mm. The cooler, equipped with a cooling jacket through which water passes, has a cylindrical shape and, with an internal diameter of 20 mm, has a height of 1600 mm.
    The dust collected by the filter is continuously introduced into the reactor, and the fluidized gas is pseudo-gas preheated to 1400 ° C (heating 12). The latter is similar
    five
    Example 2 from an acidic waste gas incinerator. In addition, 5% NH4Cl in terms of the mass of dust collected by the filter is injected into the reactor as an additive. The flow rate of the dust captured by the filter is about 1 g / s, and the flow rate of the carrier gas is about 1 dm3 / s relative to the normal state; - neither. Thus, in a reactor at a temperature of 1000 ° C, a flow rate of about 0.55 m / s is obtained, in a cooler, 12.5 m / s at the inlet and about 5 m / s at the outlet. The connected separator is designed as a cyclone and is designed and adjusted so that the coarser fraction is separated to a particle size of less than 5 µm with at least a 95% degree of separation.
    The dust is examined, as in the previous examples, before and after separation. Get the following result
    Analyze- Before Separation- After Sepavanation of the Radio
    total mass
    g10.0 8.4
    Content
    Zn% 3.3 0.3
    Content
    Pb,% 0.8 0.1
    Content
    Cd% 0,050,0005
    At the same time, samples of dust collected by the filter are dissolved according to Example 1, and the solutions obtained therewith are examined for the content of heavy metal ions:
    Severe Before Separation- After Sepalization (mg / L Radio (mg / L)
    solution of Zn2 + solution 160043
    Pbg 130.9
    Cd24-370,2
    Example 4. In a continuous operation unit, the dust collected by the filter from the incinerator is treated. The reactor consists of heat-resistant ceramics and has heat insulation in the form of a shirt, also made of a ceramic material and slag. The cylindrical inner space has a diameter of 200 mm and a height of 800 mm. The stainless steel cooler is made up of three cylindrical tubes connected in parallel with an inner diameter of 25 mm and a length of 1800 mm each.
    ten
    398586
    Nitrogen in the amount of 4 dm3 / s (in terms of the normal state), heated to a temperature of 1300 ° C, is used as a carrier gas to transfer excess physical heat per portion of the loaded material and cover all heat losses. Heated dust collected by the filter is introduced into the reactor in an amount of about 1 g / s. At the same time coke powder (85% C) is introduced in an amount of about 0.05 g / s, which is 4% C based on dust. caught by the filter. The separator, designed as an electrostatic precipitator, has a separation degree of 92% for particles with a diameter of less than 3 microns. The fine fraction is returned to the circulation system by means of a recirculation pump, the dust is analyzed before and after separation:
    15
    20
    25
    thirty
    35
    0
    Samples of dust collected by the filter are dissolved according to example 1, and the resulting solutions are examined for the content of heavy metal ions:
    Heavy metal
    five
    Zn2 +
    24 to separation (mg / l of solution) 1600 13
    Cd24
    37
    II p and me 5,
    0
    five
    After separation (mg / l solution) 8
    No reliable information. Same.
    In the experimental installation according to example 3 process the dust collected by the filter from the incinerator,
    The dust collected by the filter is continuously introduced into the reactor and fluidized. Nitrogen preheated to 1200 ° C is used as carrier gas. At the same time, 3% by volume of CO, in terms of volume, was injected into the reactor as an additive.
    nitrogen. Thus, a reactive (reducing) mixture is obtained. The amount of dust collected by the filter per volume of gas is about 150 g / m3, the consumption of dust collected by the filter is about 0.15 g / s, and the flow rate of the carrier gas is about 1 dm3 / s . The average flow rate from reactor 4 at a temperature of 1000 ° C is about 0.5 m / s and the average flow rate in the inlet cooler is about 12 m / s and about 5 m / s at the outlet. A cyclone is used as a separator.
    The dust is examined before and after separation as in the previous examples.
    I
    The following values are obtained:
    In addition, samples of dust collected by the filter are leached with a saturated C0g aqueous solution, and alkaline solutions are examined for the content of heavy metal ions:
    After separation (mg / l solution) 122 4.2 4.2
    For example, for continuous operation, the ash collected from the electrostatic precipitator from the incineration plant is treated. The ash collected by the filter is first fluidized in the mixer with nitrogen (flow rate about 0.14 dm3 / s) and then loaded into an electrically heated reactive furnace. At the same time, the fluidized mixture is heated to 1100 ° C and kept at this temperature for 3 seconds. In this case, most of the heavy metal compounds evaporate and enter the gas phase. The gas (mixture of particles) then passes through a cylindrical cooler with an inner diameter of 10 mm, on the inner wall of which condensed heavy metal compounds are condensed. Cooled containing particles substantially purified from
    five
    five
    heavy metal compounds, a gas stream is introduced into a dust trap filter where dust is separated. The analysis gives the following result:
    Analyze- Before Separation- After Sepavanation of the Radio
    total mass
    g8,0 6,5
    Content
    Zn% 3.3 0.07
    Content
    Pb,% 0.8 0.02
    Content
    Cd% 0,050,001
    Samples of the dust collected by the filter are dissolved with saturated COg water. At the same time, the following content of heavy metals in solution is obtained: Severe Prior to separation- After separation-metallization (mg / liter (mg / l
    solution) solution)
    1600
    13
    37
    0
    45
    0.9
    0.8
    Zn2 Pb2 + Cd2- Example7. In a small pilot plant, the dust collected by the filter from the incinerator is prepared. The reactor, made of ceramic material, is shaped like a hollow cylinder with a conical bottom. It is equipped with heating and heat insulation in the form of a shirt. The inner diameter is 40 mm, height is 240 mm. The cooler consists of a double-walled pipe with an inner diameter of 6 mm and a length of 1500 mm. The cooling jacket is filled with water as a cooling medium.
    0
    Portion of material consists of 100 g
    captured by the filter dust heated in the reactor to 1000 ° C. Simultaneously all device through a three-way valve
    5, using a vacuum pump, is gradually evacuated with a pressure drop of 10 kPa / min to a final pressure of 1 MPa (about 0.01 bar). Thus, this process took about 10 minutes.
    0 A portion of the loaded material is kept in this state for about 1 hour. At the same time, heavy metal compounds evaporate to a significant degree at a reduced rate.
    , pressure and condense, respectively, are sublimated in an elongated cooler, from where they are discharged after the end of loading through a vacuum tight device “The device is ventilated, the rest of the dust in the reactor is lowered down, and the latter is loaded in the next portion”
    Hyperfine dust blown away by the steam flow is held in the filter from the vacuum pump and periodically loaded
    The dust was analyzed before and after separation, and the following is found:
    Analyzing - Before Separation - After Separating Bathing
    g10.0 8.4
    Content
    Zn,% 3.3 0.4 Contents
    Pb,% 0.8 0.4 Cd content,% 0, Q5 0.005
    Samples collected by the filter dust are dissolved with saturated C02 water. The content of heavy metal solutions is as follows:
    Severe Before Separation- After Sepalization (mg / L Radio (mg / L)
    solution) solution) Zn24 1600 87 13 6.4 Cd2 + 37 1.7
    EXAMPLE 8 Filter dust captured from an incinerator before removing heavy metal compounds is mechanically prepared so that it is divided into more
    coarser and finer fractions. i
    Fresh carrier gas is introduced into the mixer using a fan. The flow rate is about 0.55 dm3 / s. From the dust bin, the dust collected by the filter was fed into the mixer so that a suspension of about 100 grams of dust per m3 was formed. The mixture thus pseudo-liquefied was transported in a cold state through a cyclone, where a larger fraction was separated with a particle diameter of more than 5 µm. This fraction accounts for about 98% of the mass of all the dust. It is fed directly to the installation for the recovery of heavy metal compounds. The dust passing through the cyclone, transported by the carrier gas, constitutes about 2% of the mass of the initial amount of dust and was introduced into the recycling facility. This dust is separated in
    39858
    ten

    ten
    15
    20
    25
    thirty
    35
    40
    45
    50
    55
    ultrathin dust filter and processed separately.
    The dust captured by the filter is heated in the reactor to the evaporation temperature of recoverable heavy metal compounds at the existing partial pressure, and the resulting vapor is thermally separated from the dust particles, while the mixture is cooled, and the vapor is converted into liquid or sublimation by condensation, solidification solid state of aggregation. At least one part of the carrier gas in the fluidization process is returned by the gaseous medium as a circulating gas in a circular process to the loading point of the dust collected by the filter. The carrier gas is preferably preheated so that the overall heat balance — regardless of loss — is covered with its physical heat. Thus, high heat transfer coefficients are achieved for heating a portion of the feed material.
    The mode can be carried out in principle continuously or cyclically. In the latter case, the work can also be carried out cyclically without a carrier gas at a greatly reduced partial pressure for the evaporated compounds of heavy metals or under vacuum. Thus, the evaporation temperature can be significantly reduced, the evaporation process is accelerated, and the yield of heavy metal compounds in the sublimate condensate increases. In principle, in all the processes captured by the filter, solid, liquid or gaseous substances can be additionally introduced into the reactor, while they are introduced into the dust itself or mixed into the carrier gas or introduced directly into the reactor. These substances affect the portion of the loaded material physically and / or chemically, while they accelerate the evaporation of heavy metal compounds by lowering the evaporation temperature, converting heavy metals into more volatile substances, and so on.
    Metal halides, ammonium halides or reducing agents, preferably carbon or carbon monoxide, are preferably added. The advantage is that the dust collected by the filter, before the compounds of heavy metals are removed in a cold state, is mechanically purely separated into a larger and finer fraction, and each fraction is separately recycled. Separation can occur mechanically, pneumatically or hydraulically using cyclones; electrostatic precipitators, dry filters, scrubbers, etc. The coarser fraction enters the plant for the extraction of heavy metals, the finer fraction — into the plant for concentration, agglomeration, briquetting and storage (final storage), etc.
    权利要求:
    Claims (4)
    [1]
    1. A method for extracting heavy non-ferrous compounds, mainly from filter-collected waste incineration plants, flue gas dedusting and gas cleaning plants, including heating the dust collected by the filter in the reactor to the evaporation temperature of heavy non-ferrous compounds to be removed, cooling the vaporized compounds in cooler, transferring them to a liquid or solid state, solidification and / or sublimation and subsequent unloading, characterized in that
    o
    five
    0
    five
    0
    In order to remove heavier non-ferrous metals more completely, fine dust particles with a particle size of less than 5 µm, separated by mechanical, or hydraulic, or pneumatic means or filtration, before evaporation of heavy non-ferrous metal compounds are separated from the dust collected by the filter and the rest of the dust collected by the filter served to the reactor.
    [2]
    2 "Pop-up method 1, about tl and h ay - -sch and with the fact that fresh heated carrier gas heated before passing through the perforated bottom up to 1100 before passing through the perforated bottom is passed to the heated dust collected by the filter - 1400 ° C, with part of the carrier gas as the circulating gas is mixed with fresh carrier gas before heating. /
    [3]
    3. A method according to claim 2, characterized in that the fresh carrier gas and the circulating gas are introduced into the reactor to form a fluidized dust layer above the perforated bottom,
    [4]
    4. A method according to, characterized in that the fine dust from the cooler is sucked off by means of dilution counter-current to the condensable compound of light non-ferrous metals and separated by filtration.
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    同族专利:
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    JPS4997774A|1973-01-25|1974-09-17|
    GB1602376A|1977-06-09|1981-11-11|Encomech Eng Services Ltd|Material separation|
    DE3018319A1|1979-05-18|1980-11-27|Niro Atomizer As|METHOD FOR REMOVING MERCURY FROM EXHAUST GASES|
    LU81330A1|1979-05-30|1980-12-16|Arbed|PROCESS AND PLANT FOR THE RECOVERY OF IRON, ZINC AND LEAD CONTAINED IN DUST AND SLUDGE FROM BLAST FURNACES, AS WELL AS CONVERTERS AND ELECTRIC STEEL FURNACES|
    JPS595354B2|1981-02-19|1984-02-03|Yamaguchikyoei Kogyo Kk|
    AT380901B|1984-09-28|1986-07-25|Voest Alpine Ag|METHOD FOR RECOVERING METALS FROM METAL-OXIDE-CONTAINING HOSPITAL DUST AND SYSTEM FOR CARRYING OUT THE METHOD|
    FR2581656B1|1985-05-10|1987-07-03|Maillet Alain|ELECTROTHERMAL PROCESS FOR SEPARATING AND REFINING METALS FROM RECOVERY PRODUCTS AND INSTALLATION FOR IMPLEMENTING SAME|
    US4673431A|1986-01-08|1987-06-16|Bricmont & Associates, Inc.|Furnace dust recovery process|
    EP0274037A1|1986-12-10|1988-07-13|BBC Brown Boveri AG|Process and device for the separation of particles|
    DE3784324D1|1986-12-10|1993-04-01|Bbc Brown Boveri & Cie|METHOD AND DEVICE FOR SEPARATING AND / OR REVOLVING PARTICLES.|AT394102B|1989-01-26|1992-02-10|Sgp Va Energie Umwelt|METHOD FOR COMBINED DISMANTLING OF ORGANIC COMPOUNDS AND REMOVAL OF HG, PB AND CR FROM DUST-BASED RESIDUES THERMAL DISPOSAL PROCESSES|
    DE3925399A1|1989-08-01|1991-02-07|Rheinische Braunkohlenw Ag|METHOD FOR REFURBISHING ACTIVE CARBON LOADED WITH HEAVY METAL|
    JPH03196887A|1989-12-26|1991-08-28|Takuma Co Ltd|Ash treating device in refuse incinerator|
    DE4035777A1|1990-11-08|1992-05-14|Noell Gmbh|METHOD FOR THE DISPOSAL OF DUST CONTAINING TOXIC HEAVY METALS, TOXIC ORGANIC MATERIALS AND SIMILAR COMPOUNDS|
    DE4109126A1|1991-03-20|1992-09-24|Aquamot Ag|METHOD FOR TREATING COMBUSTION AND / OR SMOKE GAS CLEANING RESIDUES|
    DE4120277A1|1991-06-19|1992-12-24|Krupp Polysius Ag|METHOD AND DEVICE FOR PURIFYING EXHAUST GASES FROM OVEN PLANTS|
    US5245120A|1991-12-27|1993-09-14|Physical Sciences, Inc.|Process for treating metal-contaminated materials|
    DE4342494C1|1993-12-07|1995-07-20|Mannesmann Ag|Method and device for separating heavy metals and compounds containing heavy metals|
    DE102009036950A1|2009-08-11|2011-03-03|Polysius Ag|Process and installation for separating mercury from exhaust gases from a cement production process|
    CN109701382A|2019-02-28|2019-05-03|兖矿集团有限公司|A kind of dispersion of ultrafine powder and spraying system and its processing method and purposes|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    CH267787|1987-07-15|
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